!!!永井篤志 博士の業績リスト !!総説 +Organoboron Conjugated Polymers **__Atsushi Nagai__; Yoshiki, Chujo. In ''Conjugated Polymer Synthesis - Methods and Reactions'', Wiley-VCH, Weinheim, accepted. +Luminescent Organoboron Conjugated Polymers **__Atsushi Nagai__; Yoshiki, Chujo. ''Chem. Lett.'' '''2010''', ''39'', 430-435. !![原著論文] !'''査読有り''' +Red/Near-Infrared Emissive Organic-Inorganic Hybrids Doped with Covalently Bound Boron Dipyrromethene (BODIPY) Dyes via Microwave-Assisted One-Pot Process **Kajiwara, Y.; __Nagai, A.__; Chujo, Y. ''submitted''. +Energy Transfer from Aggregation-Induced Emissive ''o''-Carborane **Kokado, K.; __Nagai, A.__; Chujo, Y. ''submitted''. +Highly NIR Emissive Di(iso)indomethene BODIPY-Based Polyfluorene: Drastic Change from Deep-Red to NIR Emission via Quantitative Polymer Reaction **Yoshii, R.; __Nagai, A.__; Chujo, Y. ''submitted''. +BODIPY-Based Chain Transfer Agent: Reversibly Thermoswitchable Luminescent Gold Nanoparticle Stabilized by BODIPY-Terminated Water-Soluble Polymer **__Nagai, A.__.; Yoshii, R.; Otsuka, T.; Kokado, K.; Chujo, Y. ''Langumir'' '''2010''', accepted. +High Near-Infrared Photoluminescence from Aza-BODIPY-Based Conjugated Polymers **Yoshii, R.; __Nagai, A.__; Chujo, Y. ''J. Polym. Sci., Part A: Polym. Chem.'' '''2010''', accepted. +Poly(γ-glutamic acid) Hydrogels with Water-Sensitive Luminescence Derived from Aggregation-Induced Emission of ''o''-Carborane **Kokado, K.; __Nagai, A.__; Chujo, Y. ''Macromolecules'' '''2010''', ''43'', 6463-6468. +Synthesis of π-Conjugated Polymers Containing Organoboron Benzo[h]quinolate in the Main-chain **Tokoro, Y.; __Nagai, A.__; Chujo, Y. ''Macromolecules'' '''2010''', ''43'', 6229-6233. +Synthesis of highly luminescent organoboron polymers connected by bifunctional 8-aminoquinolate linkers **Tokoro, Y.; __Nagai, A.__; Chujo, Y. ''J. Polym. Sci., Part A: Polym. Chem.'' '''2010''', in press. +Nanoparticle via H-Aggregation of Amphiphilic BODIPY Dyes **Tokoro, Y.; __Nagai, A.__; Chujo, Y. ''Tetrahedron Lett.'' '''2010''', ''51'', 3451-3454. +Luminescent Alternating Boron Quinolate-Fluorene Copolymers Exhibiting High Electron Mobility **__Nagai, A.__; Kobayashi, S.; Nagata, Y.; Kokado, K.; Taka, H.; Kita, H.; Suzuri, Y.; Chujo, Y. ''J. Mater. Chem.'' '''2010''', ''20'', 5190-5201. +Microwave-Assisted One-Pot Synthesis of Luminescent Organic -Inorganic Hybrid via Simultaneous Process of Sol-Gel and Suzuki Coupling Reaction **Kajiwara, Y.; __Nagai, A.__; Chujo, Y. ''Chem. Lett.'' '''2010''', ''39'', 480-481. +Microwave-Assisted Preparation of Intense Luminescent BODIPY-Containing Hybrids with High Photostability and Solvent Resistance **Kajiwara, Y.; __Nagai, A.__; Chujo, Y. ''J. Mater. Chem.'' '''2010''', ''20'', 2985-2992. +Aromatic Ring-Fused BODIPY-Based Conjugated Polymers Exhibiting Narrow Near-Infrared Emission Bands **__Nagai, A.__; Chujo, Y. ''Macromolecules'' '''2010''', ''43'', 193-200. (selected as Noteworthy Chemistry in ACS) +Thermoresposive Fluorescent Water-Soluble Copolymers Containing BODIPY Dye: Inhibition of H-Aggregation of the BODIPY Units in their Copolymers by LCST **__Nagai, A.__; Kokado, K.; Miyake, J.; Chujo, Y. ''J. Polym. Sci., Part A: Polym. Chem.'' '''2010''', ''48'', 627-634. +Luminescent Chiral Organoboron 8-Aminoquinolate-Coordination Polymers **Tokoro, Y.; __Nagai, A.__; Chujo, Y. ''Appl.Organomet.Chem.'' '''2010''', ''24'', 563-568. +Quantum Yield and Morphology Control of BODIPY-Based Supramolecular Self-Assembly with a Chiral Polymer Inhibitor **__Nagai, A.__; Kokado, K.; Miyake, J.; Chujo, Y. ''Polym. J.'' '''2010''', ''42'', 37-42. (Invited)(selected as FEATURED ARTICLES) +Microwave-Assisted Synthesis of Poly(2-hydroxyethylmethacrylate) (HEMA)/Silica Hybrid Using In Situ Polymerization Method **Kajiwara, Y.; __Nagai, A.__; Chujo, Y. ''Polym. J.'' '''2009''', ''41'', 1080-1084. +Synthesis and Photostability of Poly(p-phenylenevinylene-borane)s **__Nagai, A.__; Murakami, T.; Nagata, Y.; Kokado, K.; Chujo, Y. ''Macromolecules'' '''2009''', ''42'', 7217-7220. +Highly Luminescent Nanoparticles: Self-Assembly of Well-Defined Block Copolymers by Strong π-π Stacked BODIPY Dyes as only a Driving Force **__Nagai, A.__; Kokado, K.; Miyake, J.; Chujo, Y. ''Macromolecules'' '''2009''', ''42'', 5446-5452. +Aza-Wittig Polymerization: Kinetic Study and Efficient End Functionalization of Poly(azomethine)s **Miyake, J.; Tsuji, Y.; __Nagai, A.__; Chujo, Y. ''Macromolecules'' '''2009''', ''42'', 3463-3468. +Synthesis of Organoboron Quinoline-8-thiolate and -selenolate Complexes and their Incorporation into π-Conjugated Polymer Main-Chain **Tokoro, Y.; __Nagai, A.__; Kokado, K.; Chujo, Y. ''Macromolecules'' '''2009''', ''42'', 2988-2993. +Synthesis of Helical Polymers with a Pentasilane Core **Morisaki, M.; Otaka, H.; __Nagai, A.__; Naka, K.; Chujo, Y. ''Chem. Lett.'' '''2009''', ''38'', 498-499. +Nanofiber Formation via Self-Assembly of a Chiral Regioregular Poly(azomethine) **Miyake, J.; Tsuji, Y.; __Nagai, A.__; Chujo, Y. ''Chem. Commun.'' '''2009''', 2183-2185. +A Facile Synthesis of Chiral Luminescent Organoboron Polymers by Hydroboration Polymerization Utilizing Chiral Borane **__Nagai, A.__; Miyake, J.; Kokado, K.; Nagata, Y.; Chujo, Y. ''Macromolecules'' '''2009''', ''42'', 1560-1564. +Highly Luminescent BODIPY-Based Organoboron Polymer Exhibiting Supramolecular Self-Assemble Structure **__Nagai, A.__; Miyake, J.; Kokado, K.; Nagata, Y.; Chujo, Y. ''J. Am. Chem. Soc.'' '''2008''', ''130'', 15276-15278. +1,3-Diketone-Based Organoboron Polymers: Emission by Extending Conjugation along a Polymeric Ligand **__Nagai, A.__; Kokado, K.; Nagata, Y.; Chujo, Y. ''Macromolecules'' '''2008''', ''41'', 8295-8298. (selected as SYNFACT of the month) +Highly Intense Fluorescent Diarylboron Diketonate **__Nagai, A.__; Kokado, K.; Nagata, Y.; Arita, M.; Chujo, Y. ''J. Org. Chem.'' '''2008''', ''73'', 8605-8607. +Synthesis of star polymer by atom transfer radical polymerization with resorcinol multifunctional initiator: The construction of nanocapsule via hydrolysis and olefin metathesis reaction of the obtained star polymer **__Nagai, A.__; Hirabayashi, T.; Kudo, H.; Nishikubo, T. ''J. Polym. Sci., Part A: Polym. Chem.'' '''2008''', ''46'', 4879-4888. +Convenient synthesis of poly(γ-benzyl-L-glutamate) from activated urethane derivatives of γ-benzyl-L-glutamate **Kamei, Y.; __Nagai, A.__; Sudo, A.; Nishida, H.; Kikukawa, K.; Endo, T. ''J. Polym. Sci., Part A: Polym. Chem.'' '''2008''', ''46'', 2649-2657. +Synthesis and crosslinking behavior of a novel linear polymer bearing 1,2,3-triazole and benzoxazine groups in the main chain by a step-growth click-coupling reaction **__Nagai, A.__; Kamei, Y.; Wang, X. S.; Omura, M.; Sudo, A.; Nishida, H.; Endo, T. ''J. Polym. Sci., Part A: Polym. Chem.'' '''2008''', ''46'', 2316-2325. +Controlled thioacyl group transfer (TAGT) polymerization of cyclic sulfide: Novel approach to AB diblock copolymers by the combination of RAFT and TAGT polymerizations **__Nagai, A.__: Koike, N.; Kudo, H.; Nishikubo, T. ''Macromolecules'' '''2007''', ''40'', 8129-8131. +Synthesis of polythiourethane-based macro chain transfer agents and their block copolymers with vinyl monomers via controlled multimode polymerization **__Nagai, A.__; Hamagchi, T.; Kikukawa, K.; Kawamoto, E.; Endo, T. ''Macromolecules'' '''2007''', ''40'', 6454-6456. +Naphthalene-based spiro cyclic monomer undergoing selective radical and cationic polymerization **__Nagai, A.__; Kikukawa, K.; Kawamoto, E.; Endo, T. ''Macromolecules'' '''2007''', ''40'', 4127-4129. +Biosynthesis and Biodegradability of Copolythioesters from 3,3’-Thiodipropinic Acid and Plant Oils by Cupuriviadus necatora **Kamei, Y.; __Nagai, A.__; Nishida, H.; Kimura, H.; Endo, T. ''Macromol. Biosci.'' '''2007''', ''7'', 364-372. +Chiroptical inversion induced by sandwiching in chiral polythiourethane **__Nagai, A.__; Ochiai, B.; Endo, T. ''Chem. Commun''. '''2006''', 1515-1517. +Controlled synthesis of thermoresponsive polymers derived from L-proline via RAFT polymerization **Mori, H.; Iwaya, H.; __Nagai, A.__; Endo, T. ''Chem. Commun''. '''2005''', 4872-4874. +Cyclopolymerization of Bisacrylamide Derived from a-Pinene through Larger Chiral Ring Formation **__Nagai, A.__; Ochiai, B.; Endo, T. ''Macromolecules'' '''2005''', ''38'', 2547-2549. +A Facile Synthesis of Chiral Isocyanate-phenol and Unsymmetrical Urea Derived from Tyrosine without Protecting Phenolic Hydroxyl Groups **__Nagai, A.__; Ochiai, B.; Endo, T. ''Lett. Org. Chem.'' '''2005''', ''2'', 404-406. +Observation of Optical Activity in Polythiourethane Obtained by the Controlled Cationic Ring-opening Polymerization of Chiral Cyclic Thiourethane Derived from Serine **__Nagai, A.__; Ochiai, B.; Endo, T. ''J. Polym. Sci., Part A: Polym. Chem.'' '''2004''', ''43'', 1554-1561. +Cationic Ring-opening Polymerization of Optically Active N-Substituted Cyclic Thiourethanes **__Nagai, A.__; Ochiai, B.; Endo, T. ''Macromolecules'' '''2004''', ''37'', 7538-7542. +Synthesis and Radical Polymerization of a Novel Macromonomer Obtained by Living Cationic Ring-opening Polymerization of an Optically Active Cyclic Thiourethane by a New Inititaor Carrying Styryl Group **__Nagai, A.__; Ochiai, B.; Endo, T. ''Macromolecules'' '''2004''', ''37'', 4417-4421. +A Facile Synthesis of N-Carboxyanhydrides and Poly(α-amino acid) Using Di-tert-butyltricarbonate **__Nagai, A.__; Sato, D.; Ishikawa, J.; Ochiai, B.; Kudo, H.; Endo, T. ''Macromolecules'' '''2004''', ''37'', 2332-2334. +Synthesis of Optically Active Polyurethanes by Self-Polyaddition of Tyrosine-Based Monomers **__Nagai, A.__; Ishikawa, J.; Kudo, H.; Endo, T. ''J. Polym. Sci., Part A: Polym. Chem.'' '''2004''', ''42'', 1143-1153. +Controlled Cationic Ring-Opening Polymerization of 1,3-Oxazolidine-2-thione Derived from L-Serine **__Nagai, A.__; Miyagawa, T.; Kudo, H.; Endo, T. ''Macromolecules'' '''2003''', ''36'', 9335-9339. +Living cationic ring-opening polymerization by water-stable initiator: synthesis of a well-defined optically active polythiourethane **__Nagai, A.__; Ochiai, B.; Endo, T. ''Chem. Commun''. '''2003''', 3018-3019. +Synthesis and Self-Polyaddition of Optically Active Monomers Derived from Tyrosine **Kudo, H.; __Nagai, A.__; Ishikawa, J.; Endo, T. ''Macromolecules'' '''2001''', ''34'', 5355-5357. !'''査読無し''' +Synthesis, Characterization and Cross-linking Reaction of Poly(γ-Benzyl-L-Glutamate)-Polyisoprene-Poly(γ-Bnenzyl-L-Glutamate) Triblock Copolymers **Ochiai, B.; Sato, D.; __Nagai, A.__; Endo, T, ''J. Network. Polym. Jpn'', '''2010''', ''31'', 50-58. !!ACS Polymer Preprints +Main Chain-Type Organoboron Quinolate Polymers: Synthesis and Photoluminescence Properties **Chujo Y.; Nagata, Y.; __Nagai, A.__ '' Polym. Prep. (238th American Chemical Society, National Meeting)'' '''2009''', ''45'', 16-20. +Controlled/living polymerization of cyclic and vinyl monomers derived from amino acids **Endo, T.; __Nagai, A.__; Ochiai, B.; Mori, H. ''Polym. Prep. (American Chemical Society, Division of Polymer Chemistry)'' '''2005''', ''46'', 205-206. +Controlled synthesis of polyacrylamide containing amino acid moieties via RAFT and their stimuli-responsive properties **Mori, H.; Sutoh, K.; Iwaya, H.; __Nagai, A.__; Endo, T. '' Polym. Prep. (American Chemical Society, Division of Polymer Chemistry)'' '''2005''', ''46'', 203-204. !!特許(日本) +工藤宏人・__永井篤志__・遠藤剛「光学活性を有するイソシアネート化合物の製造方法および光学活性を有するポリウレタンの製造方法」特許公開 2002-322144 (JSRと共同研究). +__永井篤志__・工藤宏人・遠藤剛「1,3-オキサゾリジン-2-チオン化合物およびその製造方法並びにポリチオウレタンおよびその製造方法」特許公開 2004-099479(JSRと共同研究). +__永井篤志__・落合文吾・遠藤剛「ポリチオウレタンの製造方法およびグラフトポリマーの製造方法」特許公開 2006-124551(JSRと共同研究). +高秀雄・硯里善幸・北弘志・__永井篤志__・中條善樹「有機エレクトロルミネッセンス素子、その製造方法、照明装置及び表示装置」特許申請中 (コニカミノルタと共同研究). !!特許(外国) +__Nagai, A.__; Ochiai, B.; Endo, T. “Method of producing a polythiourethane and method of producing a graft polymer” U. S., 2005-250926 (JSRと共同研究). +Izumi, Y.; Kawamura, M.; Kobayashi, K.; Endo, T.; __Nagai, A.__; Shichinohe, M. "Agent for preventing organ adhesion and method for preventing adhesion using the same" WO2007-132785 (明治製菓(株)と慶応大学医学部との共同研究). !!書籍 +__永井篤志__・中條善樹「無機高分子の開発最前線」、 “第1章 新規無機元素含有高分子の合成と諸機能” pp.21-36、シーエムシー出版、2009. +__永井篤志__・落合文吾・森秀晴・遠藤剛「反応性高分子の新展開」、 “第4章 アミノ酸を出発原料とする反応性高分子 2.アミノ酸系高分子の新展開” pp.60-73、シーエムシー出版、2005. !!新聞記事等 +"Organoboron 1,3-Diketonate Polymers through Post-Polymerization Chelation" (''Macromolecules'' '''2008''', ''41 (22)'', 8295-8298.) Synfacts '''2009''', 0390-0390. +"有機色素の水中発光 実現"、化学工業日報、平成21年6月12日 +"温度変化で微粒子発光”、日経産業新聞、平成22年5月14日